Effect of Water pH on the Efficiency of Eggshells in Removing Cr (VI) Ion from Water
- Authors
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Samia A. Elbahi
Department of Epidemiology and Infection ControlAuthor
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- Keywords:
- Eggshells, adsorption, pH, Cr(VI)
- Abstract
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Recently, various types of bio-adsorbents of animal or vegetable sources with minimal cost and less effort, which are obtained from domestic and agricultural waste, have been explored. In the present work, the possibility of using chicken eggshell powder as an adsorbent material to remove hexa-chromium metal from an aqueous solution was studied. Calcium carbonate, magnesium carbonate, and calcium phosphate are the primary components of eggshell powder, which in turn have a substantial and effective role in the adsorption process. In this study, 6 g of adsorbent (egg shells) was mixed with 3 mg of hexa-chromium per liter of pure water solution at a temperature of (40) °C and within the pH range (3, 6, 9). It was found that calcified eggshells have the ability to adsorb hexa-chromium ions, with a removal rate of 88.767% at pH 6 within 60 minutes.
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Adebisi, G. A., Chowdhury, Z. Z., & Alaba, P. A. (2017). Equilibrium, kinetic, and thermodynamic studies of lead ion and zinc ion adsorption from aqueous solution onto activated carbon prepared from palm oil mill effluent. Journal of Cleaner Production, 148, 958-968.
Ahmed, M. F., & Mokhtar, M. B. (2020). Assessing cadmium and chromium concentrations in drinking water to predict health risk in Malaysia. International Journal of Environmental Research and Public Health, 17(8), 2966.
Al-Obaidi, M., Kara-Zaitri, C., & Mujtaba, I. M. (2020). Wastewater treatment by reverse osmosis process. CRC Press.
Elahi, A., Arooj, I., Bukhari, D. A., & Rehman, A. (2020). Successive use of microorganisms to remove chromium from wastewater. Applied Microbiology and Biotechnology, 104(9), 3729-3743.
Ghasemi, Z., Sourinejad, I., Kazemian, H., Hadavifar, M., Rohani, S., & Younesi, H. (2020). Kinetics and thermodynamic studies of Cr (VI) adsorption using environmental friendly multifunctional zeolites synthesized from coal fly ash under mild conditions. Chemical Engineering Communications, 207(6), 808-825.
Govindarajan, C., Ramasubramaniam, S., Gomathi, T., Devi, A. N., & Sudha, P. (2011). Sorption studies of Cr (VI) from aqueous solution using nanochitosan-carboxymethyl cellulose blend. Arch Appl Sci Res, 3(4), 127-138.
Gu, Y., & Zhu, X. (2011). Speciation of Cr (III) and Cr (VI) ions using a β-cyclodextrin-crosslinked polymer micro-column and graphite furnace atomic absorption spectrometry. Microchimica Acta, 173(3), 433-438.
Gupta, V. (2009). Application of low-cost adsorbents for dye removal–a review. Journal of environmental management, 90(8), 2313-2342.
Jain, M., Garg, V. K., & Kadirvelu, K. (2010). Adsorption of hexavalent chromium from aqueous medium onto carbonaceous adsorbents prepared from waste biomass. Journal of environmental management, 91(4), 949-957.
Klatt, V., & Kunze, J. (2009). The Determination of Chromium VI in Wastewater Using GFAAS After Extraction as Diphenylcarbazide Complex. Atomic Spectroscopy, 30(6), 185-190.
Komur, B., Altun, E., Aydogdu, M., Bilgiç, D., Gokce, H., Ekren, N., Salman, S., Inan, A., Oktar, F., & Gunduz, O. (2017). Hydroxyapatite synthesis from fish bones: atlantic salmon (Salmon salar). Acta Physica Polonica, 131(3), 400-402.
Korshoj, L. E., Zaitouna, A. J., & Lai, R. Y. (2015). Methylene blue-mediated electrocatalytic detection of hexavalent chromium. Analytical chemistry, 87(5), 2560-2564.
Lee, J.-I., Kim, J.-M., Yoo, S.-C., Jho, E. H., Lee, C.-G., & Park, S.-J. (2022). Restoring phosphorus from water to soil: Using calcined eggshells for P adsorption and subsequent application of the adsorbent as a P fertilizer. Chemosphere, 287, 132267.
Liu, W.-K., Liaw, B.-S., Chang, H.-K., Wang, Y.-F., & Chen, P.-Y. (2017). From waste to health: synthesis of hydroxyapatite scaffolds from fish scales for lead ion removal. Jom, 69(4), 713-718.
Maleki, A., Hayati, B., Naghizadeh, M., & Joo, S. W. (2015). Adsorption of hexavalent chromium by metal organic frameworks from aqueous solution. Journal of Industrial and Engineering Chemistry, 28, 211-216.
Mane, C., Mahamuni, S., Kolekar, S., Han, S., & Anuse, M. (2016). Hexavalent chromium recovery by liquid–liquid extraction with 2-octylaminopyridine from acidic chloride media and its sequential separation from other heavy toxic metal ions. Arabian Journal of Chemistry, 9, S1420-S1427.
Martone, N., Rahman, G. M., Pamuku, M., & Kingston, H. S. (2013). Determination of chromium species in dietary supplements using speciated isotope dilution mass spectrometry with mass balance. Journal of agricultural and food chemistry, 61(41), 9966-9976.
Mia, M., Sayid, A., Ahmad, F., & Rahman, M. (2020). An overview of chromium removal techniques from tannery effluent. Applied Water Science, 10(9), 1-22.
Naghipour, D., Taghavi, K., Ashournia, M., Jaafari, J., & Arjmand Movarrekh, R. (2020). A study of Cr (VI) and NH4+ adsorption using greensand (glauconite) as a low‐cost adsorbent from aqueous solutions. Water and Environment Journal, 34(1), 45-56.
Peng, H., & Guo, J. (2020). Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: a review. Environmental Chemistry Letters, 18(6), 2055-2068.
Rajoriya, S., Saharan, V. K., Pundir, A. S., Nigam, M., & Roy, K. (2021). Adsorption of methyl red dye from aqueous solution onto eggshell waste material: kinetics, isotherms and thermodynamic studies. Current Research in Green and Sustainable Chemistry, 4, 100180.
Sankaran, R., Show, P. L., Ooi, C.-W., Ling, T. C., Shu-Jen, C., Chen, S.-Y., & Chang, Y.-K. (2020). Feasibility assessment of removal of heavy metals and soluble microbial products from aqueous solutions using eggshell wastes. Clean Technologies and Environmental Policy, 22(4), 773-786.
Stadelman, W. (2000). Eggs and egg products. Encyclopedia of Food Science and Technology: Wiley and sons, Newyork.
Tsai, W.-T., Hsien, K.-J., Hsu, H.-C., Lin, C.-M., Lin, K.-Y., & Chiu, C.-H. (2008). Utilization of ground eggshell waste as an adsorbent for the removal of dyes from aqueous solution. Bioresource technology, 99(6), 1623-1629.
Tsai, W., Yang, J., Lai, C., Cheng, Y., Lin, C., & Yeh, C. (2006). Characterization and adsorption properties of eggshells and eggshell membrane. Bioresource technology, 97(3), 488-493.
Zhang, T., Tu, Z., Lu, G., Duan, X., Yi, X., Guo, C., & Dang, Z. (2017). Removal of heavy metals from acid mine drainage using chicken eggshells in column mode. Journal of environmental management, 188, 1-8.
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- 2022-09-30
- Issue
- Vol. 37 No. 3 (2022)
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Copyright (c) 2022 سامية الباهي

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