Synthesis of Plasma-Polymerized Toluene Coatings by Microwave Discharge
- Authors
-
-
Suleiman Musa Elhamali
Libyan center for plasma research, Tripoli, LibyaAuthor
-
- Keywords:
- Corrosion protection, plasma enhanced chemical vapor deposition, toluene coatings
- Abstract
-
Plasma- polymerized coatings were successfully applied on aluminum alloy, AA2024, surface for corrosion protection. The plasma polymerization process was carried out by low pressure microwave plasma at room temperature. The effect of microwave plasma power on the corrosion resistance of polymer coatings was investigated using the potentiodynamic polarization technique. As the microwave plasma power increased, the relative protective efficiency increased. Polymer coatings on alloy surfaces suppressed both anodic and cathodic reactions. The increment in protective efficiency was due to a higher degree of cross-linking in the coating. These findings suggest that the toluene polymer coatings provide a considerable protection barrier for aluminum alloys.
- Downloads
-
Download data is not yet available.
- References
-
Abd El-Hameed, A. M., & Abdel-Aziz, Y. (2021). Aluminium Alloys in Space Applications: A Short Report. Journal of Advanced Research in Applied Sciences and Engineering Technology, 22(1), 1-7.
Aramaki, K. (1999). Protection of iron corrosion by ultrathin two-dimensional polymer films of an alkanethiol monolayer modified with alkylethoxysilanes. Corrosion Science, 41(9), 1715-1730.
Ardic, M., & Gifvars, A. (2017). A study on the effects of the process parameters of polymerised HMDSO using RF-PECVD in corrosion protection applications.
Ates, M. (2016). A review on conducting polymer coatings for corrosion protection. Journal of adhesion science and Technology, 30(14), 1510-1536.
Bowen, J., & Cheneler, D. (2019). The stability and degradation of PECVD fluoropolymer nanofilms. Polymer Degradation and Stability, 160, 203-209.
Enos, D. G., & Scribner, L. L. (1997). The potentiodynamic polarization scan. Solartron Instruments, Hampshire, UK, Technical Report, 33.
Esbayou, M., Bentiss, F., Casetta, M., Nyassi, A., & Jama, C. (2018). Optimization of cold plasma process parameters for organosilicon films deposition on carbon steel: Study of the surface pretreatment effect on corrosion protection performance in 3 wt% NaCl medium. Journal of Alloys and Compounds, 758, 148-161.
Fermi, Y., Kihel, M., Sahli, S., & Raynaud, P. (2019). Synthesis of nanopowders in a PECVD reactor from organosilicon precursor. Phosphorus, Sulfur, and Silicon and the Related Elements.
Grundmeier, G., Thiemann, P., Carpentier, J., & Barranco, V. (2003). Tailored thin plasma polymers for the corrosion protection of metals. Surface and Coatings Technology, 174, 996-1001.
Jaritz, M., Hopmann, C., Wilski, S., Kleines, L., Rudolph, M., Awakowicz, P., & Dahlmann, R. (2019). Thin plasma polymerised coatings for corrosion protection against strong alkaline solutions. Surface and Coatings Technology, 374, 232-241.
Ji, Y., Cho, J.-H., & Chae, H.-S. (2013). Surface modification of aluminum by toluene plasma at low-pressure and its surface properties. Applied Surface Science, 280, 518-522.
Joo, J., Quan, Y. C., & Jung, D. (2000). Effects of plasma power on the properties of low-k polymerlike organic thin films deposited by plasma-enhanced chemical vapor deposition using the toluene precursor. Journal of Materials Research, 15(1), 228-230.
Krtouš, Z., Hanyková, L., Krakovský, I., Nikitin, D., Pleskunov, P., Kylián, O., Sedlaříková, J., & Kousal, J. (2021). Structure of plasma (re) polymerized polylactic acid films fabricated by plasma-assisted vapour thermal deposition. Materials, 14(2), 459.
Martin, P. M. (2009). Handbook of deposition technologies for films and coatings: science, applications and technology. William Andrew.
Mitev, D., Radeva, E., Peshev, D., Cook, M., & Peeva, L. (2016). PECVD polymerised coatings on thermo-sensitive plastic support. Journal of Physics: Conference Series,
Natishan, P., McCafferty, E., Donovon, E., & Hubler, G. (1995). The use of surface modification techniques for the corrosion protection of aluminum and aluminum alloys. Advances in coatings technologies for corrosion and wear resistance coatings.
Navas, R., Rajan, A. J., Topno, U. R., & Chaitanya, S. (2015). Optimizing the Coating Parameters for Coated Aluminium Alloy 2024 T351 by using Factor Analysis Method. Applied Mechanics and Materials,
Nozawa, K., & Aramaki, K. (1999). One-and two-dimensional polymer films ofmodified alkanethiol monolayers for preventing iron fromcorrosion. Corrosion Science, 41(1), 57-73.
Olajire, A. A. (2018). Recent advances on organic coating system technologies for corrosion protection of offshore metallic structures. Journal of Molecular Liquids, 269, 572-606
Singh-Beemat, J., Iroh, J. O., & Feng, L. (2013). Mechanism of corrosion protection of aluminum alloy substrate by hybrid polymer nanocomposite coatings. Progress in Organic Coatings, 76(11), 1576-1580.
Tsuji, N., Nozawa, K., & Aramaki, K. (2000). Ultrathin protective films prepared by modification of an N, N-dimethylalkylamine monolayer with chlorosilanes for preventing corrosion of iron. Corrosion Science, 42(9), 1523-1538.
Wang, T. F., Lin, T., Yang, D., Antonelli, J., & Yasuda, H. (1996). Corrosion protection of cold-rolled steel by low temperature plasma interface engineering: I. Enhancement of E-coat adhesion. Progress in Organic Coatings, 28(4), 291-297.
Yan, M., Tallman, D., Rasmussen, S., & Bierwagen, G. (2009). Corrosion control coatings for aluminum alloys based on neutral and n-doped conjugated polymers. Journal of the Electrochemical Society, 156(10), C360.
Yu, Y., Kim, J., Cho, S., & Boo, J. (2003). Plasma-polymerized toluene films for corrosion inhibition in microelectronic devices. Surface and Coatings Technology, 162(2-3), 161-166.
Zhou, Y., Rossi, B., Zhou, Q., Hihara, L., Dhinojwala, A., & Foster, M. D. (2020). Thin Plasma-Polymerized Coatings as a Primer with Polyurethane Topcoat for Improved Corrosion Resistance. Langmuir, 36(4), 837-843.
Zuo, M., Wu, T., Xu, K., Liu, S., Zhao, D., & Geng, H. (2015). Sol–gel route to ceria coatings on AA2024-T3 aluminum alloy. Journal of Coatings Technology and Research, 12(1), 75-83.
- Downloads
- Published
- 2022-12-31
- Issue
- Vol. 37 No. 4 (2022)
- Section
- Articles
- License
-
Copyright (c) 2022 Suleiman Musa Elhamali

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright of the articles Published by Almukhtar Journal of Science (MJSc) is retained by the author(s), who grant MJSc a license to publish the article. Authors also grant any third party the right to use the article freely as long as its integrity is maintained and its original authors and cite MJSc as the original publisher. Also, they accept the article remains published by the MJSc website (except in the occasion of a retraction of the article).
How to Cite
Similar Articles
- Majuldeen F. Albarani, Nwara A. Mohamed, Mohammed A. Saeed, Sensitivity of Some Apple Varieties Grown in Regions of Al-Jabal Al-Akhdar to Apple Scab Disease , Al-Mukhtar Journal of Sciences: Vol. 37 No. 4 (2022)
- Mohamed A. Mussa, M. E. Ehwaeti , A. A. El-Maleh, The Damage of diferent densities of M. incognita and M. javanica on tomato cv. Rio grand , Al-Mukhtar Journal of Sciences: Vol. 11 No. 1 (2004)
- Ibtisam, M. Lashger, Zahra,I. El gali , Hanan A Khalifa, Isolation and identification of seed borne fungi on dry bean and determination of their location on seed coats , Al-Mukhtar Journal of Sciences: Vol. 33 No. 1 (2018)
- K.A Faraj, F. M Eldoumi, N.M Momen, O.R Elssaady, Long term effects of pretreated municipal sewage water on some physical and chemical properties of soils under semiarid conditions , Al-Mukhtar Journal of Sciences: Vol. 3 No. 1 (1996)
- Nawara A. Mohamed , Amna A. Al-Mabrouk , Kawther A. Al-Senousi , Effect P. oligandrum and its filtrated on growth of some phytopathogenic , Al-Mukhtar Journal of Sciences: Vol. 32 No. 1 (2017)
- Mohammed. A. Balah , Abdel-Rahman Gamal Aldin , Zidane. H. Zidan, Sayed. A. Dahroug, Photo and thermal degradation of Glyphosate and Fluazifop-butyl herbicides with and without additives , Al-Mukhtar Journal of Sciences: Vol. 32 No. 2 (2017)
- Abdullah Ibrahim Mohammed, Salih Hamd Bieyu, Bacillus thuringiensis Berliner Allergy Mosquito larvae Different doses of pesticides , Al-Mukhtar Journal of Sciences: Vol. 1 No. 1 (1992)
- Mohammad S El-Geundi, Assanousi A Abufares, Adsorption Kinetics of an Insecticide Diazinon onto Natural Clay , Al-Mukhtar Journal of Sciences: Vol. 28 No. 1 (2013)
- Abubaker Ali Yousif Alghoul, Tarek Mohamed Fayez, Marow Moftah Ali Ahssona, Studying the possibility of using Calcium Orthophosphate as a promising dental treatment of caries by analyzing the Infrared spectrum of inspected teeth samples , Al-Mukhtar Journal of Sciences: Vol. 37 No. 1 (2022)
- Nwara A. Mohamed, Hajir H. Alalm, Effect of Pea Seed Solarization on Seed-Borne Fungi and its Vitality , Al-Mukhtar Journal of Sciences: Vol. 37 No. 1 (2022)
You may also start an advanced similarity search for this article.











