Adsorption Kinetics of an Insecticide Diazinon onto Natural Clay
- Authors
-
-
Mohammad S El-Geundi
Chemical Engineering Department, Faculty of Engineering, Omar Al-Mukhtar UniversityAuthor -
Assanousi A Abufares
Chemical Engineering Department, Faculty of Engineering, Omar Al-Mukhtar UniversityAuthor
-
- Keywords:
- Natural clay, Diazinon, Adsorption Kinetics, Mass Transfer Coefficient
- Abstract
-
The external mass transfer model has been used to predict the rate-controlling step for the adsorption of an insecticide diazinon onto natural clay. The external mass transfer coefficients (Ks) have been determined and correlated with respect to three variables namely, agitation speed, initial concentration, and mass of clay. It has been found that Ks varies with the variables studied and may be correlated with (rpm)0.93, (C0)-0.96, and (m)-0.41. The external mass transfer coefficient as the dimensionless mass transfer term Sh/Sc1/3 has been correlated with the design variables. It has also been found that Sh/Sc1/3 varies linearly with the variables studied and may be correlated with system variables via the equation:
- Downloads
-
Download data is not yet available.
- References
-
Bird, R.B., Stewart, W.E. and Lightfoot, E.N. (1960) Transport phenomena. John Wiley & Sons, INC., 1st edition, 642-648.
Brunauer, S., Emmett, P.H. and Teller, E. (1932) Adsorption of gases in multi molecular layers. J Am Chem Soc, 6, 309-319.
El-Geundi, M.S. (1990) Adsorption equilibria of basic dyestuffs onto maize cob. Adsorption Sci. Technol., 7, 114-123.
El-Geundi, M.S. (1996) Adsorption kinetics for cationic dyestuffs on to natural clay. Adsorption Sci. Technol., 13, 295-307.
El-Geundi, M.S., Farrag, T.E. and Abd El-Ghany, H.M. (2005) Adsorption equilibrium of a herbicide pendimethalin onto natural clay. Adsorption Sci. Technol., 23, 437-453.
El-Geundi, M.S., Ismail, H.M. and Attyia, K.M.E. (1995) Activated clay as an adsorbent for cationic dyestuffs. Adsorption Sci. Technol., 12, 109-115.
Furusawa, T. and Smith, J.M. (1973a) Fluid-particle and intraparticle mass transport rates in slurries. Ind Eng Chem Fundam, 12, 197-203.
Furusawa, T., and Smith, J. M. (1973b) Diffusivities from dynamic adsorption data. AIChE Journal, 19, 401-403.
Furusawa, T. and Smith J.M. (1974) Intraparticle mass transport in slurries by dynamic adsorption Studies. AIChE J., 20, 88-93.
Lemic, J., Kovacevic, D., Tomasevic, M., Stanic, T., and Pfend, R. (2006) Removal of atrazine, lindane and diazinon from water by organo-zeolites, Water Research, 40, 1079-1085.
McKay, G., Allen, S.J., McConvey, I.F. and Otterburn, M.S. (1981) Transport process in the sorption of colored ions by peat particles. J. Colloid Interface Sci., 80, 323-339.
Murray, H.H. (2000) Traditional and new applications for kaolin, smectite, and palygorskite: a general overview. Applied Clay Science, 17, 207-221.
Shariff, M.R. (2012) Kinetic and thermodynamic study for adsorption – desorption of diazinon with copper in the presence of surfactant. Global Journal of Science Frontier Research Chemistry. 12, 16-31.
Srinivasan, R. (2011) Advances in application of natural clay and its composites in removal of biological, organic and inorganic contaminants from drinking water. Advances in Materials Science and Engineering, 2011, 1-17.
Wilke, C.R. and Chang, P. (1955) Correlation of diffusion coefficients in dilute solutions. AIChE J., 1, 264-270.
Zadaka, D., Nir, S., Radian, A. and Mishael, Y.G. (2009) Atrazine removal from water by polycation-clay composites: effect of dissolved organic matter and comparison to activated carbon, Water Research, 43, (3), 677-683.
- Downloads
- Published
- 2013-06-30
- Issue
- Vol. 28 No. 1 (2013)
- Section
- Articles
- License
-

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright of the articles Published by Almukhtar Journal of Science (MJSc) is retained by the author(s), who grant MJSc a license to publish the article. Authors also grant any third party the right to use the article freely as long as its integrity is maintained and its original authors and cite MJSc as the original publisher. Also, they accept the article remains published by the MJSc website (except in the occasion of a retraction of the article).
How to Cite
Most read articles by the same author(s)
- Mohammad S El-Geundi, Assanousi A. Abufares, Adsorption Equilibria of an Insecticide Diazinon onto Natural Clay , Al-Mukhtar Journal of Sciences: Vol. 28 No. 1 (2013)
Similar Articles
- Taib. Farag Hesean, Competitive effects of wild Radish Raphanus raphanistrum.L on The growth and yield of wheat Triticum Durum. In Jabal Akhdaar (Libya) , Al-Mukhtar Journal of Sciences: Vol. 9 No. 1 (2002)
- S. A Abugarsa, J. S. Algosni, Study of Forage Value and its Seasonal Alterations for Some Perennial Grazing Plants in AL-Jabal AL-Akhdar, Libya , Al-Mukhtar Journal of Sciences: Vol. 31 No. 2 (2016)
- Galal Elmanfe Elmanfe, Textural properties of prepared alumina, stania and iron oxide catalysts , Al-Mukhtar Journal of Sciences: Vol. 29 No. 1 (2014)
- Salih Hamd Bieyw, Aabdallah Iibrahim Muhamad, Maseud Muhamad Qadih, Muhamad Aldarawi Aleayib, Fatimat Altuwmi, Nasir Muhamad Alsaahili, Hydrobiology of the Great Man-Made river reservoirs , Al-Mukhtar Journal of Sciences: Vol. 4 No. 1 (1997)
- Wasan S. Hussain, Noor Al.Huda A. Taher, Mahmoud M. Abbas, Allelopathic Effects of Chickpea on Anatomical Traits of Wheat Varieties Triticum aestivum L , Al-Mukhtar Journal of Sciences: Vol. 36 No. 4 (2021)
- A. M. Younis, D. E. Watt, M. Yacob, S. Kilcoyne, B. A. Goodman, Characterization of the Iron Phases in Some Soils from The Jabal Al–Akhdar Region of North–East Libya Using Mossbauer Spectroscopy , Al-Mukhtar Journal of Sciences: Vol. 7 No. 1 (2000)
- Galal M. Elmanfe, Osama E. Khreit , Omukalthum A. Abduljalil , Najah M. Abbas , Determination of Para-Phenylenediamine (PPD) in Henna Samples Collected from Libyan Local Markets Using HPLC , Al-Mukhtar Journal of Sciences: Vol. 37 No. 1 (2022)
- Hanan Ali Idris , Mohammed Ali Khalifa Omar, Allelopathy effects of Salvia triloba L. on seeds germination of Hordeum vulgane L., Zea mays L., Avena sativa L. and Ceratonia siliqua L. , Al-Mukhtar Journal of Sciences: Vol. 33 No. 1 (2018)
- Ahmed Ibrahim Ekhmaj, Abdul Rahman Ahmed Alriyani, Mohamed Melad Dulayoum, Evaluation of Groundwater Quality in the South of Tripoliand its suitability for Irrigation Using Irrigation Water Quality Index (IWQI) , Al-Mukhtar Journal of Sciences: Vol. 36 No. 1 (2021)
- Ezzudin S. M. Ali, Hesaien M. Mustafa, Khansa A. Omar Blkasem, Morphological variation of Libyan carob (Ceratonia siliqua L.) , Al-Mukhtar Journal of Sciences: Vol. 34 No. 2 (2019)
You may also start an advanced similarity search for this article.











