Determining the Levels of Some Heavy Metals in Springs and Groundwater Wells in the Northeastern Region of Libya
- Authors
-
-
Ifdial O El Awamy
شعبه المبيدات, قسم وقاية النبات, كلية الزراعة, جامعة عمر المختار، البيضاء- ليبيAuthor -
Ruqayah. A. A Abduljalil
Department of Plant Protection, Pesticide Chemistry, Faculty of Agriculture, Omar Almukhtar University, Al-Bayda -LibyaAuthor -
Omukalthum A. A Abduljalil
Department of Plant Protection, Pesticide Chemistry, Faculty of Agriculture, Omar Almukhtar University, Al-Bayda -LibyaAuthor
-
- Keywords:
- Heavy Metals, Northeastern Region, Springs and Groundwater Wells
- Abstract
-
This study was designed to detect heavy metals (Zn, Cd, Pb, and Cu) in several springs and groundwater wells in the northeastern region of Libya. Samples were collected from different regions in both seasons (dry and wet). An atomic absorption spectrophotometry equipped with Slotted Tube Atomic Trap (STAT) was used. The limit of detection (LOD) was in the range of 0.008 to 0.03 μg mL-1, and the limit of quantification (LOQ) was in the range of 0.02 to 0.09 μg mL-1. % RSD (relative standard deviations) ranged between 0.0001 to 0.329%. Results showed the presence of heavy metal residues in the regions in two seasons (dry-wet) during the study in some springs and groundwater wells. The zinc (Zn), cadmium (Cd), and Copper (Cu) values were below permitted limits, according to the World Health Organization (WHO), Libyan National Center for Standardization (LNCSM), and Food and Agriculture Organization (FAO). Lead (Pb) in the dry season was much higher than the wet season in accordance with WHO and LNCSM. The other values were below permissable limits according to WHO, LNCSM, and FAO. This study’s results show the presence of dangerous levels of lead during the dry season in the groundwater wells on SahlAlmarj I, Alabyar III. Overall, the investigation of chemical and agricultural fertilizers is an effective method of monitoring the quality of drinking water. Such investigations are needed to identify possible sources of contamination of storage tanks and pipelines to ensure the delivery of safe drinking water to end-users.
- Downloads
-
Download data is not yet available.
- References
-
Abdolgader, R. E., Hussain, R. A., Hasan, S. M., & Agoub, A. A. (2013). Quantitative Determination of Cd and Pb in Tissues and Organs of Chickens Raised in El-Jabel Alakhder Region—Libya. Food and Nutrition Sciences, 4(08), 763.
Ahmad, J. U., & Goni, M. A. (2010). Heavy metal contamination in water, soil, and vegetables of the industrial areas in Dhaka, Bangladesh. Environmental monitoring and assessment, 166(1-4), 347-357.
Ahmed, M., Matsumoto, M., Ozaki, A., Thinh, N. V., & Kurosawa, K. (2019). Heavy metal contamination of irrigation water, soil, and vegetables and the difference between dry and wet seasons near a multi-industry zone in Bangladesh. Water, 11(3), 583.
APHA. (1995). Standard methods for the examination of water and wastewater. American Public Health Association, American Water Works association, Water Environment Federation, Washington(5), 4-12.
Benti, G. (2014). Assessment of heavy metals in vegetables irrigated with Awashi River in selected farms around Adama town, Ethiopia. African journal of environmental science and technology, 8(7), 428-434.
Bhaskar, C. V., Kumar, K., & Nagendrappa, G. (2010). Assessment of heavy metals in water samples of certain locations situated around Tumkur, Karnataka, India. Journal of Chemistry, 7(2), 349-352.
Boran, M., & Altınok, I. (2010). A review of heavy metals in water, sediment and living organisms in the Black Sea. Turkish Journal of Fisheries and Aquatic Sciences, 10(4).
Chang, M. B., Jen, C. H., Wu, H. T., & Lin, H. Y. (2003). Investigation on the emission factors and removal efficiencies of heavy metals from MSW incinerators in Taiwan. Waste Management & Research, 21(3), 218-224.
Deniseger, J., Erickson, L., Austin, A., Roch, M., & Clark, M. (1990). The effects of decreasing heavy metal concentrations on the biota of Buttle Lake, Vancouver Island, British Columbia. Water research, 24(4), 403-416.
Dike, N., Ezealor, A., & Oniye, S. (2004). Concentration of Pb, Cu, Fe and Cd during the dry season in river Jakara, Kano, Nigeria. Chemclass Journal, 1, 78-81.
Ferner, D. (2001). Toxicity, heavy metals. Med. J, 2(5), 1.
Gaur, V. K., Gupta, S. K., Pandey, S., Gopal, K., & Misra, V. (2005). Distribution of heavy metals in sediment and water of river Gomti. Environmental monitoring and assessment, 102(1-3), 419-433.
Ghanem, M., Samhan, S., Carlier, E., & Ali, W. (2010). Groundwater pollution due to pesticides and heavy metals in North West Bank. Journal of Environmental Protection, 2(04), 429-434.
Hunt, D. T. E., & Wilson, A. L. (1986). The chemical analysis of water: general principles and techniques (Vol. 2). Royal Society of Chemistry.
Jamshaid, M., Khan, A. A., Ahmed, K., & Saleem, M. (2018). Heavy metal in drinking water its effect on human health and its treatment techniques–a review. International Journal of Biosciences, 12(4), 223-240.
Kabata-Pendias, A. (2010). Trace elements in soils and plants. CRC press.
Macklin, M., Brewer, P., Hudson-Edwards, K., Bird, G., Coulthard, T., Dennis, I., Lechler, P., Miller, J., & Turner, J. (2006). A geomorphological approach to the management of rivers contaminated by metal mining. Geomorphology, 79(3-4), 423-447.
Malassa, H., Al-Qutob, M., Al-Khatib, M., & Al-Rimawi, F. (2013). Determination of different trace heavy metals in ground water of South West Bank/Palestine by ICP/MS. Journal of Environmental Protection, 4(08), 818.
Martin, C. W. (2000). Heavy metal trends in floodplain sediments and valley fill, River Lahn, Germany. Catena, 39(1), 53-68.
Nie, N. H., Bent, D. H., & Hull, C. H. (1970). SPSS: Statistical package for the social sciences.
Phuong, N. M., Kang, Y., Sakurai, K., Iwasaki, K., Kien, C. N., Van Noi, N., & Son, L. T. (2010). Levels and chemical forms of heavy metals in soils from Red River Delta, Vietnam. Water, Air, and Soil Pollution, 207(1-4), 319-332.
Prabu, P. (2009). Impact of heavy metal contamination of Akaki River of Ethiopia on soil and metal toxicity on cultivated vegetable crops. Electronic Journal of Environmental, Agricultural & Food Chemistry, 8(9), 12-24.
Quina, M. J., Santos, R. C., Bordado, J. C., & Quinta-Ferreira, R. M. (2008). Characterization of air pollution control residues produced in a municipal solid waste incinerator in Portugal. Journal of hazardous materials, 152(2), 853-869.
Rahman, M., Ziku, A., Choudhury, T. R., Ahmad, J., & Mottaleb, M. (2015). Heavy metals contaminations in irrigated vegatables, soils, river water: A compressive study Chilmari, Kurigram, Bangladesh. Int J Environ Ecol Family Urb Stud, 5(5), 29-42.
Reza, R., & Singh, G. (2010). Heavy metal contamination and its indexing approach for river water. International Journal of Environmental Science & Technology, 7(4), 785-792.
Roy, K., Ansari, M. S., Karim, M. R., Das, R., Mallick, B., & Gain, A. K. (2015). Irrigation water quality assessment and identification of river pollution sources in Bangladesh: Implications in policy and management. J Water Resour Hydro Eng, 4(4), 303-317.
Sin, S., Chua, H., Lo, W., & Ng, L. (2001). Assessment of heavy metal cations in sediments of Shing Mun River, Hong Kong. Environment international, 26(5-6), 297-301.
Suthar, S., Nema, A. K., Chabukdhara, M., & Gupta, S. K. (2009). Assessment of metals in water and sediments of Hindon River, India: Impact of industrial and urban discharges. Journal of hazardous materials, 171(1-3), 1088-1095.
Tarla, D., Bantar, V., Mfopou, M., Fotio, D., & Fontem, D. (2018). Determination of Heavy Metal Concentration in Surface Waters of the Western Highlands of Cameroon. pathways, 1(45-46), 2-8.
Yadav, A., Yadav, P. K., & Shukla, D. (2013). Investigation of heavy metal status in soil and vegetables grown in urban area of Allahabad, Uttar Pradesh, India. International Journal of Scientific and Research Publications, 3(9), 1-7.
- Downloads
- Issue
- Vol. 35 No. 4 (2020)
- Section
- Articles
- License
-

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright of the articles Published by Almukhtar Journal of Science (MJSc) is retained by the author(s), who grant MJSc a license to publish the article. Authors also grant any third party the right to use the article freely as long as its integrity is maintained and its original authors and cite MJSc as the original publisher. Also, they accept the article remains published by the MJSc website (except in the occasion of a retraction of the article).
How to Cite
Similar Articles
- Salah M Hamad, GIS-Based Groundwater Information System (GWIS) of Al Waseetah area: Case study , Al-Mukhtar Journal of Sciences: Vol. 34 No. 1 (2019)
- Ifdial Omer EL-Awami , Rabaha M. ELJarari, Monitoring of Organochlorine Pesticides and Certain Heavy Metal Residues in Selected Vegetables and Fruits Collected from Eastern Libyan Markets , Al-Mukhtar Journal of Sciences: Vol. 36 No. 4 (2021)
- Ismail A. Ajaj, wafaa Amhimmid, Hala Ismail, Tahani Al-Arabi, Khawla Al-Oraibi, Determination of Heavy Metals in Henna Leaves and Cosmetic Henna Products Available in Zliten, Libya , Al-Mukhtar Journal of Sciences: Vol. 37 No. 2 (2022)
- Masoud.M.M. Zatout, Yousef K. A. Abdalhafid, Salmeen. H. Alhage, Effect of Wastewater on Heavy Metal Accumulation in Cystoseria sp. (Brown algae) and Enteromorpha. sp. (Green algae) in Derna Coast, Libya , Al-Mukhtar Journal of Sciences: Vol. 33 No. 2 (2018)
- Ahmeda A. Alzagtat, Alsury A. Alsury, Bee Honey as a Bioindicator of Environmental Pollution with Some Heavy Metals in Zawia and Janzour Regions, Libya , Al-Mukhtar Journal of Sciences: Vol. 38 No. 1 (2023)
- Ahmed Ibrahim Ekhmaj, Abdul Rahman Ahmed Alriyani, Mohamed Melad Dulayoum, Evaluation of Groundwater Quality in the South of Tripoliand its suitability for Irrigation Using Irrigation Water Quality Index (IWQI) , Al-Mukhtar Journal of Sciences: Vol. 36 No. 1 (2021)
- Z.I El-Gali, O.M. El-ssunossie, H. A. Khlifa, Studies on Alternaria and Pestalotiopsis Fungi Causing Foliar Diseases of Pistacia lentiscus In Some Locales at Mid Region of Al-Jabal Al-Akhdar , Al-Mukhtar Journal of Sciences: Vol. 33 No. 1 (2018)
- Ezzudin S. M. Ali, Hesaien M. Mustafa, Khansa A. Omar Blkasem, Morphological variation of Libyan carob (Ceratonia siliqua L.) , Al-Mukhtar Journal of Sciences: Vol. 34 No. 2 (2019)
- Ammar A Ammar, Hydrological Spatial Analysis of Wadi Alkuf Catchment Area, Cyrenaica, Northeastern Libya , Al-Mukhtar Journal of Sciences: Vol. 33 No. 3 (2018)
- Ramadan E. Abdolgader, Salem O. El-Fergani, Yahya Khamis Ardia, Status of food consumed in the Great Jamahiriya in terms of food additives and pollutants , Al-Mukhtar Journal of Sciences: Vol. 8 No. 1 (2001)
You may also start an advanced similarity search for this article.











